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Developers can start building voice experiences for customers in Brazil using the new Portuguese for Brazil voice model. Skills that developers create now and are certified for publication will be available for customers when Alexa launches in Brazil later this year.
Developer documentation can be found here: https://developer.amazon.com/docs/custom-skills/develop-skills-in-multiple-languages.html
Currently pt-PT is not an available feature. For any upcoming announcements you can stay tuned to our blogs: https://developer.amazon.com/blogs/alexa/